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Set the boot order so that HDD is 1 then CD/DVD then USB. The BIOS should go down the line until it fits a bootable drive with an OS of some kind on it. You should/could also, if your mobo is new enough, press an F-key I believe F11 in most cases and it'll bring up a boot menu to which you can then select the drive to boot from, in your case select your USB device.
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